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Organic Chemistry

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Alkanes

Revision Notes

Key Points

  • Alkanes are a class of saturated hydrocarbons with the general formula C_n H_(2n+2)
  • Alkanes are non-polar molecules due to the equal sharing of electrons in the C-H and C-C bonds
  • Alkanes form a homologous series, where each successive member differs by a CH_2 group
  • The boiling and melting points of alkanes increase with increasing carbon chain length
  • Alkanes are named using the IUPAC (International Union of Pure and Applied Chemistry) system

Definition

Alkanes are a class of saturated hydrocarbons with the general formula C_n H_(2n+2), where n is the number of carbon atoms in the molecule.

Characteristics

  • Alkanes are non-polar molecules due to the equal sharing of electrons in the C-H and C-C bonds.
  • They have a tetrahedral arrangement of atoms around each carbon atom.
  • Alkanes are the simplest organic compounds and are considered the parent compounds of organic chemistry.

Homologous Series

  • Alkanes form a **homologous series**, where each successive member differs by a CH_2 group.
  • The boiling point of alkanes increases with increasing carbon chain length.
  • The melting point of alkanes also increases with increasing carbon chain length.

Nomenclature

  • Alkanes are named using the **IUPAC (International Union of Pure and Applied Chemistry) system**.
  • The name is derived from the root word that indicates the number of carbon atoms, followed by the suffix "-ane".
  • Branched alkanes are named by identifying the longest carbon chain and the position and type of substituents.